diff --git a/datafusion/functions/src/core/named_struct.rs b/datafusion/functions/src/core/named_struct.rs
index 6ae17f055e651..8973e836d33e7 100644
--- a/datafusion/functions/src/core/named_struct.rs
+++ b/datafusion/functions/src/core/named_struct.rs
@@ -27,7 +27,9 @@ use std::sync::Arc;
 
 #[user_doc(
     doc_section(label = "Struct Functions"),
-    description = "Returns an Arrow struct using the specified name and input expressions pairs.",
+    description = "Returns an Arrow struct using the specified name and input expressions pairs.
+For information on comparing and ordering struct values (including `NULL` handling),
+see [Comparison and Ordering](struct_coercion.md#comparison-and-ordering).",
     syntax_example = "named_struct(expression1_name, expression1_input[, ..., expression_n_name, expression_n_input])",
     sql_example = r#"
 For example, this query converts two columns `a` and `b` to a single column with
diff --git a/datafusion/functions/src/core/struct.rs b/datafusion/functions/src/core/struct.rs
index 476da39a5ab2d..2697cb46b09f0 100644
--- a/datafusion/functions/src/core/struct.rs
+++ b/datafusion/functions/src/core/struct.rs
@@ -27,7 +27,9 @@ use std::sync::Arc;
     doc_section(label = "Struct Functions"),
     description = "Returns an Arrow struct using the specified input expressions optionally named.
 Fields in the returned struct use the optional name or the `cN` naming convention.
-For example: `c0`, `c1`, `c2`, etc.",
+For example: `c0`, `c1`, `c2`, etc.
+For information on comparing and ordering struct values (including `NULL` handling),
+see [Comparison and Ordering](struct_coercion.md#comparison-and-ordering).",
     syntax_example = "struct(expression1[, ..., expression_n])",
     sql_example = r#"For example, this query converts two columns `a` and `b` to a single column with
 a struct type of fields `field_a` and `c1`:
diff --git a/docs/source/user-guide/sql/scalar_functions.md b/docs/source/user-guide/sql/scalar_functions.md
index 5a8ef4db3d4b2..022b0f9daec86 100644
--- a/docs/source/user-guide/sql/scalar_functions.md
+++ b/docs/source/user-guide/sql/scalar_functions.md
@@ -4709,6 +4709,8 @@ _Alias of [string_to_array](#string_to_array)._
 ### `named_struct`
 
 Returns an Arrow struct using the specified name and input expressions pairs.
+For information on comparing and ordering struct values (including `NULL` handling),
+see [Comparison and Ordering](struct_coercion.md#comparison-and-ordering).
 
 ```sql
 named_struct(expression1_name, expression1_input[, ..., expression_n_name, expression_n_input])
@@ -4750,6 +4752,8 @@ _Alias of [struct](#struct)._
 Returns an Arrow struct using the specified input expressions optionally named.
 Fields in the returned struct use the optional name or the `cN` naming convention.
 For example: `c0`, `c1`, `c2`, etc.
+For information on comparing and ordering struct values (including `NULL` handling),
+see [Comparison and Ordering](struct_coercion.md#comparison-and-ordering).
 
 ```sql
 struct(expression1[, ..., expression_n])
diff --git a/docs/source/user-guide/sql/struct_coercion.md b/docs/source/user-guide/sql/struct_coercion.md
index d2a32fcee2650..059f9fd009b00 100644
--- a/docs/source/user-guide/sql/struct_coercion.md
+++ b/docs/source/user-guide/sql/struct_coercion.md
@@ -208,6 +208,26 @@ SELECT [
 ] FROM t_left JOIN t_right;
 ```
 
+## Comparison and Ordering
+
+DataFusion supports comparing `STRUCT` values with standard comparison operators
+(`=`, `!=`, `<`, `<=`, `>`, `>=`). Ordering comparisons are lexicographical and
+follow DataFusion's default ascending comparison behavior, where `NULL` sorts
+before non-`NULL` values.
+
+### Examples
+
+```sql
+SELECT {x: 1, y: 2} < {x: 1, y: 3};
+-- true
+
+SELECT {x: 1, y: NULL} < {x: 1, y: 2};
+-- true
+
+SELECT {x: 1, y: NULL} = {x: 1, y: NULL};
+--true
+```
+
 ## Migration Guide: From Positional to Name-Based Matching
 
 If you have existing code that relied on **positional** struct field matching, you may need to update it.
diff --git a/docs/source/user-guide/sql/subqueries.md b/docs/source/user-guide/sql/subqueries.md
index 692d1c4020d74..7533bd49d553d 100644
--- a/docs/source/user-guide/sql/subqueries.md
+++ b/docs/source/user-guide/sql/subqueries.md
@@ -102,6 +102,18 @@ SELECT * FROM x WHERE column_1 NOT IN (1,3);
 +----------+----------+
 ```
 
+#### `IN` with tuple-like values and `NULL`
+
+For tuple-like values, `IN` uses DataFusion's struct equality semantics:
+
+```sql
+SELECT (1, 1) IN ((1, NULL));
+-- false
+
+SELECT (1, NULL) IN ((1, NULL));
+-- true
+```
+
 ## SELECT clause subqueries
 
 `SELECT` clause subqueries use values returned from the inner query as part